Diode equation
A diode’s distinctive feature is that it conducts current in one direction, but not the other. The diode’s $i$$v$ behavior can be modeled by the nonlinear Shockley diode equation. We will cover the details of that equation in this article.
Written by Willy McAllister.
Contents
Where we’re headed
The $i$$v$ curve of a diode is modeled by this nonlinear equation,
$i = \text I_\text S \left ( e^{\,qv/k\text T} 1 \right )$
terms
$i$ is the current through the diode.
$\text I_{\text S}$ is the reverse saturation current. For silicon it's typically $10^{12}\,\text{ampere}$.
$e$ is the base of the natural logarithm, $2.71828\cdots$.
$q$ is the charge on an electron, $1.602 \times 10^{19} \,\text{coulomb}$.
$v$ is the voltage across the diode.
$k$ is Boltzmann's constant, $1.380\times 10^{23} \,\text{joule/kelvin}$
$\text T$ is the temperature in kelvin. Room temperature is about $300\,\text{kelvin}$.
Diode $i$$v$ equation
The diode $i$$v$ relationship can be modeled with an equation. This equation is based on the physics underlying the diode action, along with careful measurements on real diodes.
$i = \text I_\text S \left ( e^{\,qv/k\text T} 1 \right )$
The equation covers the range of a few volts on either side of the origin. It does not model where the diode breaks down far to the left on the voltage axis.
The plot above looks more like a sharp elbow than an exponential curve. The exponentialness shows up if we zoom in close to the origin $(\text{milliamperes}$ $\rightarrow$ $\text{picoamperes})$.
At this scale you can see the tiny negative reverse saturation current $\text I_{\text S}$ flowing backwards through the diode when the diode is reverse biased.
For a silicon diode, a typical value for $\text I_{\text S}$ is $10^{12}\,\text A$, $1$ picoampere.
For a germanium diode, a typical $\text I_{\text S}$ is quite a bit higher, $10^{6}\,\text A$, $1$ microampere.
Inside the diode $i$$v$ equation
This section dives into the diode equation in some detail. It is okay to skip to the diode circuit example in the next article.
There are many parameters in the diode equation. Let’s go through them carefully.
$i = \text I_\text S \left ( e^{\,qv/k\text T} 1 \right )$
Look for $v$, the voltage across the diode. It’s up in the exponent. This is why current has an exponential dependence on voltage.
Now let’s look at the other stuff up in the exponent. We know exponents have no dimensions, so the other terms in the exponent $(q/k\text T)$ have to end up with units of $1/\text{volts}$.

$q$ is the charge on an electron, in coulombs: $q = 1.602 \times 10^{19} \,\text C$.

$k$ is the Boltzmann constant: $k = 1.380\times 10^{23} \,\text{J/K}\,\text{(joules per kelvin)}$

$\text T$ is the temperature measured from absolute zero in $\text{kelvin}$ or $\text K$.
Boltzmann’s constant is the scale factor that tells you the average energy of a particle in a gas (an atom or small molecule). A particle at $\text T = 300\,\text K$, (room temperature) has an average kinetic energy of $k\text T$,
$k\text T = 1.380\times 10^{23} \,\text{J/K}\cdot 300\,\text K = 4.14\times 10^{21}\,\text J$
If the particle happens to be an electron, we can talk about its energy per charge,
$\dfrac{k\text T}{q} = \dfrac {4.14 \times 10^{21}\,\text J} {1.602\times 10^{19}\,\text C} = 25.8 \,\dfrac{\text J}{\text C}$
Energy per charge might sound familiar. Its other name is voltage,
$\dfrac{k\text T}{q} = 25.8 \,\dfrac{\text J}{\text C} = 25.8 \,\text{mV}$
At room temperature, $k\text T/q$ is about $26$ millivolts. That represents the kinetic energy of an average everyday roomtemperature electron. If your diode is at room temperature, the diode equation becomes,
$i = \text I_\text S \left ( e^{\,v/26\text{mV}} 1 \right )$
When the diode voltage is greater than $26\,\text{mV}$ the exponent term grows rapidly. When the diode voltage is less than $26\,\text{mV}$, the exponent term is small and the $1$ term dominates.
Boltzmann's constant
The Boltzmann constant is a very important number in physics. It connects the world we see and sense with the atomicscale world of atoms and electrons.
Suppose you have a chamber filled with gas molecules. You can measure the temperature of the chamber (a macroworld measurement with a thermometer). As the chamber gets warmer, down at the atomic level the gas molecules have higher kinetic energy. If you know the temperature of the gas, the Boltzmann constant $k$ relates the temperature to the average kinetic energy of a molecule. $k$ shows up wherever behavior at the atomic level is related to what happens in the macro world. Diodes conducting current is one such case. There are tons of others.
The units of Boltzmann's constant are joules per kelvin. Physicists write Boltzmann's constant as $k_B$.
David Santo Pietro, KA's physics fellow tells you more about Boltzmann's constant.
"per kelvin" sounds funny
Temperature can be measured in "degrees Celsius", or "degrees Fahrenheit", or "kelvin." We write temperatures as $23^\circ\text C$ or $73^\circ\text F$, with the little circle $^\circ$degree symbol.
The units of absolute temperature are kelvin. Kelvin are defined to already be degrees. So it's proper to say "kelvin" instead of "degrees Kelvin", since that would be redundant. The temperature in kelvin is written without the little degree circle, like this: $300\,\text K$.
The size of a kelvin is the same as a degree Celsius. The only difference is the kelvin scale starts at absolute $0$ and the Celsius scale starts at the freezing point of water. A temperature of absolute zero, or $0\,\text K$, is the same as $273\,^{\circ}\text C$.
Try not to confuse big $\text K$ the unit for kelvin with little $k$ for Boltzmann's constant.
300 K is a nice warm room
$300\,\text K$ is $27^{\circ}\text C$ or $80^{\circ}\text F$, which is a pretty warm room. Engineers like round number that are easy to remember, so we use $300\,\text K$ for room temperature. This is close enough for circuit design.
kT on q
My physics teacher pronounced $k\text T/q$ as "kT on q". I always liked the sound of that. The reciprocal is, of course, "q on kT".
Diodes are sensitive to temperature
Since temperature $\text T$ appears in the diode $i$$v$ equation, we know the diode curve changes at different temperatures. Increasing temperature shifts the $i$$v$ curve to the right.
Summary
A diode is modeled by this equation,
$i = \text I_\text S \left ( e^{\,qv/k\text T} 1 \right )$
$\text I_{\text S}$ is the saturation current. For silicon diodes a typical saturation current is $\text I_{\text S}=10^{12}\,\text A$. $k$ is Boltzmann’s constant, $\text T$ is the temperature in kelvin, and $q$ is the charge on an electron in coulombs.
The term $k\text T/q $ is equivalent to $26\,\text{mV}$ if the diode is near room temperature $(300\,\text K)$.
Near room temperature, the diode equation can be written as,
$i = \text I_\text S \left ( e^{\,v/26\text{mV}} 1 \right )$
Questions
Increasing temperature will actually increase the current, not decrease it as in your plot. The reason is that the Is factor increases rapidly with temperature.